TCPP (Tris(1-Chloro-2-Propyl) Phosphate) | Flame Retardant Plasticizer — CAS 13674-84-5

Bastone STONEAF-TCPP is a chlorinated organophosphate flame retardant produced by Zhejiang Bastone Technology Co., Ltd.

With a phosphorus content of 9.0–9.8% and chlorine content of 32.0–32.8%, STONEAF-TCPP delivers reliable flame suppression across PU foam, PVC, EVA, acetate fiber, and phenolic systems while simultaneously improving low-temperature flexibility, moisture resistance, and antistatic performance.

Molecular Formula: C6H12Cl3O4P8

Other Synonyms: Tris(1-chloro-2-propyl) phosphate

Packaging: 200L drum; IBC

Description

TCPP (Tris(1-chloro-2-propyl) phosphate, CAS 13674-84-5) is a liquid halogenated phosphate ester that functions as both a reactive flame retardant and a secondary plasticizer. At ambient temperature it presents as a colorless to pale yellow transparent oil with a viscosity of 65–70 mPa·s at 25°C — low enough to blend cleanly into most polymer matrices without elevated processing temperatures or additional dispersing aids.

The dual flame-retardant mechanism is what makes TCPP commercially important. Phosphorus acts in the condensed phase, promoting char formation and interrupting polymer decomposition. Chlorine acts in the gas phase, scavenging free radicals in the flame front. With phosphorus at 9.0–9.8% and chlorine at 32.0–32.8%, STONEAF-TCPP achieves meaningful flame suppression with a relatively low loading level — reducing the risk of compromising mechanical or aesthetic properties in the finished part.

Tris(2-chloroisopropyl)phosphate (TCPP) is Mainly used in the flame-retardance of PVC, polystyrene, phenolic resins, acrylic resins, rubber and coating.

Density sits at 1.280–1.295 g/cm³, and the refractive index at 25°C reads 1.462–1.465. Purity is ≥98% by content, acid value is capped at ≤0.1 mgKOH/g, and moisture is controlled to ≤0.1%. These tight limits matter to formulators because acid contamination and residual moisture are the two most common sources of hydrolytic instability in phosphate ester systems — both accelerate polymer degradation and can cause discoloration or gas evolution during processing.

Beyond flame retardancy, TCPP contributes measurable secondary benefits: reduced brittleness at low temperatures, improved moisture barrier properties, and mild antistatic behavior. For flexible PVC or soft foam applications where the formulation must meet flame standards without sacrificing cold-weather performance, TCPP delivers both functions in a single additive — simplifying the formulation and reducing raw material SKU count.

Bastone manufactures STONEAF-TCPP at controlled production facilities in Hangzhou, with in-house quality verification against each specification parameter before release. Consistent batch-to-batch quality — particularly on chlorine content and acid value — is a frequent pain point when sourcing flame retardant plasticizers from trading companies that aggregate product from multiple toll manufacturers. Bastone's direct manufacturing eliminates that variability.

Factory and Activities

STONEAF-TCPP — colorless to pale yellow transparent liquid
STONEAF-TCPP — colorless to pale yellow transparent liquid, viscosity 65–70 mPa·s at 25°C.

Specifications

General Information

Property Detail
Product Name STONEAF-TCPP
Chemical Name Tris(1-chloro-2-propyl) phosphate
CAS Number 13674-84-5
Chemical Type Chlorinated organophosphate ester
Appearance Colorless or yellowish transparent oil liquid
Manufacturer Zhejiang Bastone Technology Co., Ltd

Technical Properties

Parameter Specification Unit
Content ≥98 %
Acid Value ≤0.1 mgKOH/g
Chroma (Platinum-Cobalt) ≤30 No.
Density 1.280–1.295 g/cm³
Refractive Index (25°C) 1.462–1.465
Moisture ≤0.1 %
Viscosity (25°C) 65–70 mPa·s
Phosphorus Content 9.0–9.8 %
Chlorine Content 32.0–32.8 %

Applications

Polyurethane Foam

PU foam — particularly rigid foam used in construction panels, refrigeration equipment, and spray insulation — is the largest end-use for TCPP globally. The low viscosity of STONEAF-TCPP allows direct metering into the polyol stream without heating, and the product's compatibility with standard polyether and polyester polyols is well-established. The combined phosphorus/chlorine mechanism achieves flame class compliance at loadings that do not significantly compromise foam cell structure or compressive strength. The ≤30 Pt-Co color specification ensures the foam does not yellow beyond acceptable limits for interior applications.

Flexible and Rigid PVC

In PVC applications, TCPP functions as a secondary plasticizer and flame retardant additive alongside primary plasticizers such as DOP or DOTP. Because TCPP's density (1.280–1.295 g/cm³) and refractive index are compatible with typical PVC compound parameters, it disperses evenly during calendering or extrusion without phase separation. The contribution to low-temperature flexibility is particularly relevant for wire and cable sheathing in cold-climate installations and for flexible sheeting used in commercial roofing or industrial curtains where flame standards apply.

EVA and Acetate Fiber

Ethylene-vinyl acetate compounds used in footwear, sports equipment, and foam padding benefit from TCPP's flame retardancy without the harshness associated with aluminum trihydrate or brominated alternatives. In acetate fiber processing, TCPP improves antistatic behavior — a practical benefit that reduces fiber breakage on high-speed spinning lines and decreases static-related contamination in finished textile rolls.

Phenolic and Other Thermoset Systems

Phenolic resins used in laminates and molded electrical components require flame retardancy that survives cure temperatures. TCPP's thermal stability at standard processing conditions makes it a viable additive in these systems, contributing both flame suppression and minor plasticizing effect that can reduce brittleness in unfilled phenolic parts.

TCPP in flexible PVC film and synthetic leather manufacturing
TCPP enables flexible PVC film and synthetic leather manufacturing to meet flame retardancy standards without sacrificing cold-temperature performance.
IBC tote and drum packaging for STONEAF-TCPP
IBC tote and drum packaging available; direct-manufacture supply from Hangzhou ensures batch-to-batch consistency.

Why Choose Bastone

Bastone is a direct manufacturer, not a distributor. STONEAF-TCPP is produced at Bastone's own facilities in Hangzhou Economic Development Zone, which means pricing reflects factory economics rather than a trading margin, and supply capacity is tied to Bastone's production schedule — not to spot availability on the commodity market. For buyers requiring consistent quarterly volume, that distinction matters.

Quality control at Bastone covers every specification parameter in the datasheet: purity, acid value, moisture, viscosity, chlorine content, and phosphorus content are verified on each production batch before shipment authorization. The ≥98% purity and ≤0.1 mgKOH/g acid value limits are not aspirational targets — they are release criteria. Batches that miss either threshold are not shipped.

Bastone's R&D team supports downstream formulation work. If a customer is integrating STONEAF-TCPP into a new PU foam system or a flexible PVC compound and encounters compatibility or processing issues, Bastone's technical team can assist with loading recommendations and compatibility screening. That kind of formulation support is not available from a trading company or a reference-standard vendor.

Sourcing & Logistics

Parameter Detail
Standard Packaging 200 kg drums; 1000 L IBC tanks
Bulk Option Flexitank (on request)
Export Entity Zhejiang Bastone Technology Co., Ltd
Country of Origin China (Hangzhou)
Trade Terms FOB Ningbo / Shanghai; CIF available
Documentation COA, SDS, commercial invoice, packing list, bill of lading
Sample Availability Lab samples available on request
Contact [email protected]

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